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Mai was the daughter and elder child of the former Governor of "New Ozai" and his wife. During the later years of the Hundred Year War, she became one of Princess Azula's main allies, thereby one of Team Avatar's greatest foes, as well as Prince Zuko's love interest.

Mai served as Zuko's love interest, and the couple had a relatively stable relationship throughout Avatar: The Last Airbender. However, in The Promise Part 2, Mai broke up with Zuko after knowing his secret meetings with Ozai.

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