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To some extent, she was indeed worried about Zuko. With her perception, she quickly realized that something was bothering Zuko, and as such, she wanted to know what it was, since they were allies at that time. However, during the confessions by the campfire, the little clip of her smirking while Zuko vented, to me, showed that the caring she showed earlier disappeared, replaced by her usual menacing ways. Now she knew Zuko's innermost worries, which could be useful in the future.

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